RESEARCH ON WEAR RESISTANCE OF CARBONIZED 45 STEEL BY ELECTRO-SPARK DEPOSITION TECHNOLOGY
Abstract
Electro-spark deposition (ESD) is a green manufacturing method which is more energy-efficient than traditional heat treatment methods and has minimal environmental pollution. ESD enables rapid carburization of metal surfaces by the graphite electrode. Thus, the wear resistance property of the metal surface is improved. ESD can carburize the surface of large steel structure parts in agriculture, improving wear resistance and service life. The traditional carburizing process costs much money and is difficult to achieve. ESD carburizing can save much money and even carburize the partial surface of the part. The traditional carburizing process cannot achieve these. This research employed rapid ESD equipment with rotary electrodes for the surface carburization of No.45 steel. The experiments used the Taguchi orthogonal array (OA) factorial design method. The four critical factors of the ESD process, such as energy, duty cycle, voltage and frequency, were tested. Four parameters and four levels were used to perform sixteen groups of carburizing experiments. The freestate graphite powder was removed from the surface of the deposited samples. The deposited surfaces were analyzed by X-ray diffraction (XRD). According to the diffraction pattern, the composition of the material was compared. It was found that wear-resistant Fe3 C and modified sintered graphite. The linear reciprocating dry friction experiments at room temperature were carried out with a 6mm CrO2 friction ball under 15N pressure. The ultra-deep field microscope was used to examine the experimental surfaces, and the characterization parameters were based on the abrasion marks. The parameters were characterized by an ultra-deep field microscope and analyzed according to the abrasion marks. The abrasion marks can help to obtain three feasible deposition process solutions. Finally, the extreme value design of Taguchi OA was carried out on the width of abrasion marks. The optimized process solution was obtained and verified by experiments. In this article, abrasion mark method can better characterize the wear resistance of materials than other methods. The abrasion marks method was more convenient when the interface between the coating and the substrate (such as carburized materials)was not obvious. The process scheme can help enterprises solve the carburizing process of large carbon steel parts.
References
2. Chen, L., Meng, H.-M., Huang, L.-L., & Liu, J.-Y. (2013). Microstructure and wear property of multi-layer YG8 ESD coating on 45 steel. Transactions of Materials and Heat Treatment, 34(11), 170-175. doi:CNKI:SUN:JSCL.0.2013-11-033
3. Dai, Y., Kang, L., Han, S., Li, Y., Liu, Y., Lei, S., & Wang, C. (2022). Surface hardening behavior of advanced gear steel C61 by a novel solid-solution carburizing process. Metals, 12(3), 379. doi:https://doi.org/10.3390/met12030379
4. Edenhofer, B., Joritz, D., Rink, M., & Voges, K. (2015). Carburizing of Steels. In Thermochemical surface engineering of steels (pp. 485-553): Elsevier.
5. Gaponova, O. P., Tarelnyk, V. B., Antoszewski, B., Radek, N., Tarelnyk, N. V., Kurp, P., . . . Hoffman, J. (2022). Technological features for controlling steel part quality parameters by the method of electrospark alloying using carburezer containing Nitrogen—Carbon components. Materials, 15(17), 6085. doi:https://doi.org/10.3390/ma15176085
6. Karavaev, D., Matygullina, E., Doshchennikov, M., & Sinyushov, D. (2019). Wear resistance of steel parts after electrospark alloying by graphite electrodes. Russian Engineering Research, 39(10), 889-891. doi:https://doi.org/10.3103/S1068798X19100113
7. Kirik, G., Gaponova, O., Tarelnyk, V., Myslyvchenko, O., & Antoszewski, B. (2018). Quality analysis of aluminized surface layers produced by electrospark deposition. Powder Metallurgy Metal Ceramics, 56(11), 688-696. doi:https://doi.org/10.1007/s11106-018-9944-6
8. Krishnia, L., Kumari, R., Kumar, V., Singh, A., Garg, P., S Yadav, B., & K Tyagi, P. (2016). Comparative study of thermal stability of filled and un-filled multiwalled carbon nanotubes. Advanced Materials Letters, 7(3), 230-234. doi:https://doi.org/10.5185/amlett.2016.6149
9. Mikhailyuk, A., & Gitlevich, A. (2010). Application of graphite in electrospark technologies. Surface Engineering and Applied Electrochemistry, 46(5), 424-430.
10. Nakayama, K. (1992). An overview of the excess carburizing process. International Journal of Materials Product Technology, 7(3), 245-256. doi:https://doi.org/10.1504/IJMPT.1992.036511
11. Padgurskas, J., Kreivaitis, R., Rukuiža, R., Mihailov, V., Agafii, V., Kriūkienė, R., . . . Technology, C. (2017). Tribological properties of coatings obtained by electro-spark alloying C45 steel surfaces. 311, 90-97. doi:https://doi.org/10.1016/j.surfcoat.2016.12.098
12. Reséndiz-Calderón, C., Farfan-Cabrera, L., Oseguera-Peña, J., & Rodríguez-Castro, G. (2020). Wear and friction of boride layer in CoCrMo alloy under different micro-abrasion modes (rolling and grooving abrasion). Materials Letters, 279, 128500. doi:https://doi.org/10.1016/j.matlet.2020.128500
13. Shevchenko, O. (2020). Ultrasound effect on electrospark cementation process. Paper presented at the IOP Conference Series: Materials Science and Engineering.
14. Stavitskii, B. I. (2010). Glimpses of the history of electrospark machining of materials. Surface Engineering and Applied Electrochemistry, 46(2), 178-191. doi:https://doi.org/10.3103/s1068375510020183
15. Tarelnyk, V., Haponova, O. P., & Konoplianchenko, Y. V. (2022). Electric-spark Alloying of Metal Surfaces With Graphite. Progress in Physics of Metals, 23(1), 27-58. doi:https://doi.org/10.15407/ufm.23.01.027
16. Tarelnyk, V., Konoplianchenko, I., Gaponova, O., Radionov, O., Antoszewski, B., Kundera, C., . . . Gerasimenko, V. (2022). Application of wear-resistant nanostructures formed by ion nitridizing & electrospark alloying for protection of rolling bearing seat surfaces. Paper presented at the 2022 IEEE 12th International Conference Nanomaterials: Applications &
Properties (NAP).
17. Tarelnyk, V., Martsynkovskyy, V., Gaponova, O., Konoplianchenko, I., Dovzyk, M., Tarelnyk, N., & Gorovoy, S. (2017). New sulphiding method for steel and cast iron parts. Paper presented at the IOP Conference Series: Materials Science and Engineering.
18. Tarelnyk, V., Paustovskii, A., Tkachenko, Y. G., Martsinkovskii, V., Belous, A., Konoplyanchenko, E., & Gaponova, O. (2018). Electrospark Graphite Alloying of Steel Surfaces: Technology, Properties, and Application. Surface Engineering Applied Electrochemistry, 54(2), 147-156. doi:http://doi.org/10.3103/s106837551802014x
19. Weiwei, C., Ying, Z., Hui, K., Ping, Q., Ruijun, W., & Xiaoou, H. (2007). Study on thickness of WC-8co reinforcing layer deposited by new EDM system on TC1 alloy surface. New Technology & New Process, 5(3), 93-94,112. doi:10.3969/j.issn.1003-5311.2007.05.032
20. Xiang, H., Ke, F., Tan, Y.-f., Wang, X.-l., & Hua, T. J. T. o. N. M. S. o. C. (2017). Effects of process parameters on microstructure and wear resistance of TiN coatings deposited on TC11 titanium alloy by electrospark deposition. 27(8), 1767-1776. doi:https://doi.org/10.1016/S1003-6326(17)60199-7
21. Zhu, T., Shipway, P., & Sun, W. (2019). The dependence of wear rate on wear scar size in fretting; the role of debris (third body) expulsion from the contact. Wear, 440-441, 203081. doi:https://doi.org/10.1016/j.wear.2019.203081